Mechanisms of Surface Charge Modification of Carbonates in Aqueous Electrolyte Solutions

Prediction of Surface Tension in Single and Mixed Electrolyte Solutions

Thermodynamic quantities of surface formation of aqueous electrolyte solutions: IX. Aqueous solutions of ammonium salts.

The properties of aqueous ammonium salt solutions at the air/water surface are presented. By comparison of the properties of ammonium halides solutions with those of sodium halide, we note a close similarity, which indicates that the increments in surface tension may be explained in relation to the hydration enthalpy of anions. We find that the behaviors of the salts with nitrate anions which a...

Thermodynamic Quantities of Surface Formation of Aqueous Electrolyte Solutions.

The surface tensions of binary salt mixtures made up from NaCl and MgCl2 in aqueous solution were measured as a function of concentration and temperature. By analyzing the results, the thermodynamic quantities of surface formation such as entropy (Deltas), Helmholtz free energy (Deltaf), and energy of surface formation (Deltau) were evaluated. The Deltaf of the mixtures positively deviates from...

An Evaluation of Four Electrolyte Models for the Prediction of Thermodynamic Properties of Aqueous Electrolyte Solutions

In this work, the performance of four electrolyte models for prediction the osmotic and activity coefficients of different aqueous salt solutions at 298 K, atmospheric pressure and in a wide range of concentrations are evaluated. In two of these models, (electrolyte Non-Random Two-Liquid e-NRTL and Mean Spherical Approximation-Non-Random Two-Liquid MSA-NRTL), association between ions of opposit...

SURFACE MODIFICATION OF ANALCIME FOR REMOVAL OF NITRITE AND NITRATE FROM AQUEOUS SOLUTIONS

The capacity of natural zeolites to absorb anionic pollutants from water is limited. This limitation can be overcome by modifying the surface of the minerals with organic cations. In this research, natural zeolite, Analcime was used for removing the nitrate and nitrite impurities from aqueous solutions. The surface of the zeolite was modified by tetramethylammonium and tetraethylammonium ions t...